The origin of melanophlogite, a clathrate mineral, in natrocarbonatite lava at Oldoinyo Lengai, Tanzania
Beard, Andy and Howard, K. and Carmody, L. and Jones, A.P. (2013) The origin of melanophlogite, a clathrate mineral, in natrocarbonatite lava at Oldoinyo Lengai, Tanzania. American Mineralogist 98 , pp. 1998-2006. ISSN 0003-004X.
Abstract
We report new observations of a clathrate mineral, melanophlogite [46SiO2.6(N2,CO2).2(CH4,N2)], as part of a tuffaceous layer within a sample of the 2006 natrocarbonatite lava, whose composition reflects the typical magma erupted passively at Oldoinyo Lengai throughout the last c50 yr. The mineral has been identified by chemical composition, micro-X-ray diffraction, and transmitted light optical characteristics. This is the first reported occurrence of a clathrate in an igneous carbonatite, and we conjecture that this mineral may be recognized elsewhere in alteration products of natrocarbonatite ash and in particular, combeite-bearing carbonatite lithologies. Specifically, melanophlogite is a rare polymorph of SiO2 with guest molecules (e.g., CH4, CO2, SO2, N2, OH, Xe, and Kr) within a silicate framework. It occurs in an ash pellet-rich layer within the natrocarbonatite lava, as abundant groundmass crystals and as cores of individual ash pellets, with pseudocubic and pseudohexagonal habits, ranging from 50 to 100 Rm in size, with numerous inclusions of nepheline laths aligned parallel to the crystal margins. It has high-C contents (up to 2.25 wt%) and CO2 is considered to be the guest molecule due to crystallization within an alkaline carbonatitic-CO2-rich environment.
Metadata
| Item Type: | Article |
|---|---|
| Keyword(s) / Subject(s): | Oldoinyo Lengai, melanophlogite, natrocarbonatite, combeite |
| School: | Birkbeck Faculties and Schools > Faculty of Science > School of Natural Sciences |
| Depositing User: | Sarah Hall |
| Date Deposited: | 05 May 2016 16:29 |
| Last Modified: | 02 Aug 2023 17:23 |
| URI: | https://eprints.bbk.ac.uk/id/eprint/15117 |
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