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    Structural analysis of synthetic polymer mixtures using ion mobility and tandem mass spectrometry

    Hilton, G.R. and Jackson, A.T. and Thalassinos, Konstantinos and Scrivens, J.H. (2008) Structural analysis of synthetic polymer mixtures using ion mobility and tandem mass spectrometry. Analytical Chemistry 80 (24), pp. 9720-9725. ISSN 0003-2700.

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    Abstract

    Ion mobility (IM) combined with tandem mass spectrometry (MS/MS) has been employed to separate and differentiate between polyether oligomers with the same nominal molecular weights. Poly(ethylene glycol)s with the same nominal mass-to-charge ratio (m/z), but with differing structures, were separated using ion mobility. IM-MS/MS data were able to aid identification of the backbone and end groups of the four individual polyethers in the two sets of isobaric mixtures. The MS/MS data from the resolved oligomers enabled a detailed structural characterization of the polyether mixtures to be completed in one experiment.

    Metadata

    Item Type: Article
    School: School of Science > Biological Sciences
    Research Centres and Institutes: Structural Molecular Biology, Institute of (ISMB)
    Depositing User: Administrator
    Date Deposited: 20 May 2013 11:57
    Last Modified: 06 Dec 2016 10:40
    URI: https://eprints.bbk.ac.uk/id/eprint/6893

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