Cooperative induction in double H-bonding donor/acceptor compounds: chains vs. ribbons
Prohens, R. and Portell, A. and Puigjaner, C. and Barbas, R. and Alcobé, X. and Font-Bardia, M. and Tomas, Salvador (2012) Cooperative induction in double H-bonding donor/acceptor compounds: chains vs. ribbons. CrystEngComm 18 , pp. 5745-5748.
Abstract
Two different types of monodimensional crystalline aggregates formed by squaramides, chains and ribbons, have been studied both in the solid state and ab initio with four model compounds. Although ribbons are a priori possible, only covalently forced syn conformations have been observed. Cooperative induction is postulated to explain the preference for chains instead of ribbons in squaramide crystals.
Metadata
Item Type: | Article |
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School: | Birkbeck Faculties and Schools > Faculty of Science > School of Natural Sciences |
Research Centres and Institutes: | Structural Molecular Biology, Institute of (ISMB) |
Depositing User: | Sarah Hall |
Date Deposited: | 17 Feb 2014 16:08 |
Last Modified: | 02 Aug 2023 17:09 |
URI: | https://eprints.bbk.ac.uk/id/eprint/9194 |
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