Extra-terrestrial mantle samples: Rare Earth Element variations and evidence for melt metasomatism in ureilite meteorites

Downes, Hilary and Mittlefehldt, D.W. and Ross, A.J. and Lee, C.-T. (2024) Extra-terrestrial mantle samples: Rare Earth Element variations and evidence for melt metasomatism in ureilite meteorites. Lithos 486-7 (107775), ISSN 0024-4937. (In Press)

Abstract

Ureilites are meteorites derived from the mantle of a reduced differentiated asteroid, the “Ureilite Parent Body” (UPB), which was later disrupted by impact with another solar system body. They have ultramafic compositions dominated mostly by olivine and pigeonite with rare orthopyroxene and augite; aluminous phases are generally absent. Ureilites vary from abundant peridotites to much rarer pyroxenites, and their core olivine compositions range from Fo74 to Fo97 across different samples. The UPB experienced sufficiently high temperatures to undergo silicate partial melting, as shown by depletion in the Light Rare Earth Elements (LREE) in bulk restitic ureilites. Plagioclase and merrillite were probably present in the UPB mantle but have been completely removed during silicate partial melting. Partial melts of the UPB mantle are represented by glassy melt inclusions, igneous clasts in ureilite breccias, cumulus augite in some ureilites, and rare trachyandesitic fragments. These melts are generally intermediate and sub-alkaline in composition, although a few are alkaline. They have more enriched and flatter bulk REE patterns than the restitic ureilites and often show positive Eu anomalies. Glasses (representing melts) in ureilites from this study range from 57 to 79 wt% SiO2. One sample (AhS 22) shows petrographic and geochemical evidence for interaction between magma and the solid UPB mantle by forming metasomatic augite. 2 Silicate minerals in ureilites analysed by LA-ICP-MS are generally LREE-depleted, with negative Eu anomalies. Ureilitic olivines have the lowest REE contents and the smallest negative Eu anomalies. Low-Ca pyroxenes have similar patterns with slightly stronger Eu anomalies. Augites have the highest REE contents and the most negative Eu anomalies. Augites show REE disequilibrium with olivine and low-Ca pyroxene, suggesting that they were not part of the restitic assemblage but were added by silicate melts passing through the UPB mantle, i.e. they are metasomatic in origin. We also discuss the size of the original UPB, using silicate minerals as evidence for it being a typical asteroid rather than a planet-sized object.

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